2 edition of Electrode kinetics and double layer structure. found in the catalog.
Electrode kinetics and double layer structure.
Casper Willem de Kreuk
|LC Classifications||QD571 .K8|
|The Physical Object|
|Number of Pages||75|
|LC Control Number||72170722|
The widely used microcapacitor approach of the double layer and its limitations are assessed. Observations on the influence of the electrode potential on the energetic position of surface states at the Ag-electrolyte contact are compared to the predictions of classical charge transfer models that are based on transition state theory where. from book Fuel cells: From of the theoretical aspects of the structure of the double layer, as applied to electrode/electrolyte interfaces, across which chargetransfer reactions occur, is.
Porous carbon materials have been prepared from different precursors (anthracite and carbon fibers) by different activation methods (KOH and CO2), obtaining a series of samples with very different porous texture and porous structure. Electrochemical impedance spectroscopy has been used to analyze the kinetics of the charge−discharge process during the behavior of these materials as. considered the structure of the double layer in the correla tion with electrode kinetics. (Cf. detailed bibliography in a recent paper from this laboratory (10).) Scope and Purpose of this Work. Two cases can be distinguished in double layer effects according to whether or not there is specific adsorption.
Get this from a library! Electrode kinetics and double layer structure: the Eu(II)/Eu(III) electrode reaction at the dropping mercury electrode in 1M KCI, 1M KI and 1M KSCN solutions. [Casper Willem de Kreuk; Rijksuniversiteit te Utrecht.]. Book and Media Review. Previous Article Next Article Table of Contents. Double-layer and electrode kinetics (Delahay, Paul) Double Layer and Electrode Kinetics. Journal of the American Chemical Society. Gierst. 88 (20), pp – Abstract | PDF w/ Links | Hi-Res PDF. Article Options. PDF ( KB) PDF w/ Links (0 KB).
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A double layer (DL, also called an electrical double layer, EDL) is a structure that appears on the surface of an object when it is exposed to a object might be a solid particle, a gas bubble, a liquid droplet, or a porous DL refers to two parallel layers of charge surrounding the object.
The first layer, the surface charge (either positive or negative), consists of ions. between double layer structure and electrode kinetics. First a short review of the models for the double layer is given. (For extensive reviews, see refs. 1, 4 and ) Following the double layer concept of Sterns) and Grahamea), ions cannot approach the electrode surface within a certain distance.
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Double Layer and Electrode Kinetics: Author: Paul Delahay: Publisher: Interscience Publishers, SURFACE SCIENCE 18 () North-Holland Publishing Co., Amsterdam ELECTRODE KINETICS AND DOUBLE LAYER STRUCTURE B. TIMMER, M. SLUYTERS-REHBACH and J. SLUYTERS Laboratory of Analytical Chemistry, State University, Utrecht, The Netherlands Several electrochemical methods have been developed in recent years for the study of the kinetic parameters of electrode Cited by: Relation between ksh and double-layer structure The qualitative correlation between log ksha and the amount of specific adsorption of halide ions is evident after inspection of Fig.
4 Electrode kinetics and double layer structure. book connection with ql-data% For a quantitative comparison it seems most realistic first to apply the Frumkin correction using q~2-data from refs. lO and a Cited by: ELECTRODE KINETICS AND DOUBLE-LAYER STRUCTURE qi 1 vs.
the salt activity, aK+ai- at some integral values of q (-- io to -- 12 #C cm-2). Following DUTKIEWICZ AND PARSONS 7, such plots are easily transformed into plots of q11 vs. x, the mole fraction of KI in KF +KI mixtures, after calculation of ax+ai- in i M solutions as a function of x (the mean activity coefficient is taken as constant).
Electrochemisty at Metal and Semiconductor Electrodes covers the structure of the electrical double layer and charge transfer reactions across the electrode/electrolyte interface.
The purpose of the book is to integrate modern electrochemistry and semiconductor physics, thereby, providing a quantitative basis for understanding electrochemistry at metal and semiconductor electrodes.
Lust, in Encyclopedia of Interfacial Chemistry, General Aspects. Electrical double layer structure (edl) and potential of zero charge are the fundamental characteristics of the electrode/electrolyte interface, determining the charge and mass transfer kinetics.
1–12 Edl structure determines the properties of electrical double layer capacitors and hybrid supercapacitors, various. ELECTRODE KINETICS AND DOUBLE LAYER STRUCTURE IV. THE Eu(II)/Eu(III) ELECTRODE REACTION AT THE DME IN 1 M KSCN; INFLUENCE OF COMPLEX FORMATION C.
DE KREUK, M. SLUYTERS-REHBACH ANO J. SLUYTERS Laboratory of Analytical Chemistry, State University, Utrecht (The Netherlands) (Received 26th May ) INTRODUCTION. The transport of material to and from the electrode interface Kinetics of Electron Transfer.
In this section we will develop a quantitative mThe current flowing in either the reductive or oxidative steps can be predicted using the following expressions odel for the influence of the electrode voltage on the rate of electron transfer. A detailed study has been made of the kinetics of the Eu(III)/Eu(II) electrode reaction in 1 M KCl and in 1 M KI at the dropping mercury electrode, by.
Double layer structure and adsorption kinetics of ions at metal electrodes in room temperature ionic liquids Thesis (PDF Available) January with Reads How we measure 'reads'.
(somewhat lessthan half ofthe book), whichcomprisean excellentsummary of what every student of reactors should structure of the double layer with and without specificadsorption. Thesecond Double-layer and electrode kinetics (Delahay, Paul). As early asFrumkin recognized the essential correlation between the double layer structure at the electrode interface and electrode kinetics.
As enough data for the kinetic parameters are yet available, interest is growing in this correlation, because it may result in a better understanding of heterogeneous reaction rates. The structure of the electrical layer and its effect on the kinetics of electrode processes were summarized in several reviews, among which the outstanding reviews of Damaskin , Parsons , and of Nürnberg and Stackelberg  must be mentioned.
On the Structure of the Helmholtz Layer and its Implications on Electrode Kinetics H.J. Lewerenz Joint Center for Artificial Photosynthesis, California Institute of Technology Pasadena, CA USA Concepts and selected experiments on the structure of the Helmholtz double layer at the metal- and semiconductor - electrolyte phase.
ELECTRODE KINETICS AND DOUBLE-LAYER STRUCTURE II. THE POTENTIAL-DEPENDENCE OF THE KINETIC PARAMETERS OF THE Zn2+/Zn(Hg) ELECTRODE REACTION M.
SLUYTERS-REHBACH, J. BREUKEL A~rI) J. SLUYTERS Laboratory of Analytical Chemistry, State University, Utrecht (The Netherlands) (Received February I5th, ).
The structure and charging kinetics of electrical double layers (EDLs) at interfaces of NaCl solutions and planar electrodes are studied by molecular dynamics (MD) and Poisson–Nernst–Planck (PNP) simulations.
Based on the MD results and prior experimental data, we show that counterion packing in planar EDLs does not reach the steric limit at electrode voltages.
The Electrical Double Layer. The model which gave rise to the term 'electrical double layer' was first put forward in the 's by Helmholtz.
In this model he assumed that no electron transfer reactions occur at the electrode and the solution is composed only of electrolyte.
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Langmuir. Light-Activated Ionic Gelation of. Electrode Kinetics by Eliezer Gileadi,available at Book Depository with free delivery worldwide.Double Layer and Electrode Kinetics Hardcover – January 1, by Paul Delahay (Author) out of 5 stars 2 ratings. See all formats and editions Hide other formats and editions.
Price New from Used from Hardcover "Please retry" — — — Hardcover —Reviews: 2.Overview of electrode processes (Ch.
1) Potentials and thermodynamics (Ch. 2) Electron transfer kinetics (Ch. 3) Mass transfer: convection, migration and diffusion (Ch. 4) Double-layer structures and surface adsorption (Ch. 13) Part II Techniques and Applications Potential step techniques (Ch.